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POSTSUBSCRIPT ∼ 105 Ok which can not be described by a Curie-Weiss law. POSTSUBSCRIPT symmetry might be clearly identified. In crossed polarization magnetic excitations of different symmetry can contribute to the Raman sign. POSTSUBSCRIPT, which is detected in our Raman spectra, points to such a possibility. POSTSUBSCRIPT, the compound undergoes a magnetic part transition into an extended-vary-ordered state. 25 K. Right here, an external magnetic field leads to a transition from an AFM to a ferrimagnetic state. The specific ratio of the noticed-tooth spine-spine and spine-vertex interactions may explain the instability of the dimer quantum ground state towards an incommensurate 3D magnetic order. The LSW theory can capture an incommensurate instability of the given 3D uniform lengthy-vary order beneath detection of some spin wave approaching zero vitality at a certain wave vector. It’s price repeating that this final interplay is chargeable for establishing long-range order. It’s additionally a constantly transferring target.

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